%0 Generic %A Shi, F. N. %A Cunha-Silva, L. %A Mafra, L. %A Trindade, T. %A Carlos, L. D. %A A. Almeida Paz, F. %A Rocha, J. %D 2008 %T Interconvertable Modular Framework and Layered Lanthanide(III)-Etidronic Acid Coordination Polymers %U https://acs.figshare.com/articles/dataset/Interconvertable_Modular_Framework_and_Layered_Lanthanide_III_Etidronic_Acid_Coordination_Polymers/2963827 %R 10.1021/ja074119k.s008 %2 https://acs.figshare.com/ndownloader/files/4662928 %K 3 D framework %K etidronic acid %K Coordination PolymersIsostructural %K hydrothermal synthesis stage %K Interesting photoluminescence properties %K water network %K H 5hedp %K hydrothermal synthesis %K Na %K H 2O cluster %K H 2O %K NMR %K interlayer space %K Ln %K hydration degree %K Tb %K Interconvertable Modular Framework %K sodium chloride %K framework materials %X Isostructural modular microporous Na2[Y(hedp)(H2O)0.67] and Na4[Ln2(hedp)2(H2O)2nH2O (Ln = La, Ce, Nd, Eu, Gd, Tb, Er) framework-type, and layered orthorhombic [Eu(H2hedp)(H2O)2]·H2O and Na0.9[Nd0.9Ge0.10(Hhedp)(H2O)2], monoclinic [Ln(H2hedp)(H2O)]·3H2O (Ln = Y, Tb), and triclinic [Yb(H2hedp)]·H2O coordination polymers based on etidronic acid (H5hedp) have been prepared by hydrothermal synthesis and characterized structurally by (among others) single-crystal and powder X-ray diffraction and solid-state NMR. The structure of the framework materials comprises eight-membered ring channels filled with Na+ and both free and lanthanide-coordinated water molecules, which are removed reversibly by calcination at 300 °C (structural integrity is preserved up to ca. 475 °C), denoting a clear zeolite-type behavior. Interesting photoluminescence properties, sensitive to the hydration degree, are reported for Na4[Eu2(hedp)2(H2O)2]·H2O and its fully dehydrated form. The 3D framework and layered materials are, to a certain extent, interconvertable during the hydrothermal synthesis stage via the addition of HCl or NaCl:  of the 3D framework Na4[Tb2(hedp)2(H2O)2nH2O, affords layered [Tb(H2hedp) (H2O)]·3H2O, whereas layered [Tb(H2hedp)(H2O)2]·H2O reacts with sodium chloride yielding a material similar to Na4[Tb2(hedp)2(H2O)2nH2O. In layered [Y(H2hedp)(H2O)]·3H2O, noncoordinated water molecules are engaged in cooperative water-to-water hydrogen-bonding interactions, leading to the formation of a (H2O)13 cluster, which is the basis of an unprecedented two-dimensional water network present in the interlayer space. %I ACS Publications