10.1021/cg700877n.s002 Jinfang Zhang Jinfang Zhang Yinglin Song Yinglin Song Junyi Yang Junyi Yang Mark G. Humphrey Mark G. Humphrey Chi Zhang Chi Zhang A Single-Bridge Strategy for Synthesis of a 3-D Heterobimetallic Cluster with a Heavily Distorted Diamondoid Topology and Enhanced Third-Order Nonlinear Optical Properties American Chemical Society 2008 cluster 4N cyanide bridges WS 4Cu diamondoid topology Distorted Diamondoid Topology 2008-02-06 00:00:00 Dataset https://acs.figshare.com/articles/dataset/A_Single_Bridge_Strategy_for_Synthesis_of_a_3_D_Heterobimetallic_Cluster_with_a_Heavily_Distorted_Diamondoid_Topology_and_Enhanced_Third_Order_Nonlinear_Optical_Properties/2958988 A novel three-dimensional heterobimetallic cluster {[Bu<sub>4</sub>N][WS<sub>4</sub>Cu<sub>3</sub>(CN)<sub>2</sub>]}<sub><i>n</i></sub> (<b>1</b>) with a heavily distorted diamondoid topology was constructed from the T-shaped building clusters [WS<sub>4</sub>Cu<sub>3</sub>]<sup>+</sup> and single cyanide bridges in a 4-connected mode; this cluster shows strong third-order nonlinear optical properties.