%0 Generic
%A Metrangolo, Pierangelo
%A Meyer, Franck
%A Pilati, Tullio
%A Proserpio, Davide M.
%A Resnati, Giuseppe
%D 2008
%T Dendrimeric Tectons in Halogen Bonding-Based Crystal Engineering
%U https://acs.figshare.com/articles/dataset/Dendrimeric_Tectons_in_Halogen_Bonding_Based_Crystal_Engineering/2958985
%R 10.1021/cg700870t.s003
%2 https://acs.figshare.com/ndownloader/files/5335120
%K Dendrimeric Tectons
%K DAB dendrimers
%K adduct
%K Halogen
%K generation dendrimers
%K interpenetrated sql networks
%K halogen
%K square topology
%K synthesis
%K bi
%K solution
%K NHC
%K Crystal
%K crystal lattice
%K coordination properties
%K supramolecular
%X The use of DAB dendrimers in halogen bonding-based crystal engineering is reported. The DAB-dendr-(NHC6F4I)22 self-assembles with (E)-1,2-bis-(4-pyridyl)-ethylene in a 1:2 supramolecular adduct, whose crystal lattice is composed of 5-fold interpenetrated sql networks, which is the highest degree for a square topology reported so far. The synthesis and coordination properties of higher generation dendrimers are also described, both in the liquid state and in solution.
%I ACS Publications