%0 Generic %A Metrangolo, Pierangelo %A Meyer, Franck %A Pilati, Tullio %A Proserpio, Davide M. %A Resnati, Giuseppe %D 2008 %T Dendrimeric Tectons in Halogen Bonding-Based Crystal Engineering %U https://acs.figshare.com/articles/dataset/Dendrimeric_Tectons_in_Halogen_Bonding_Based_Crystal_Engineering/2958985 %R 10.1021/cg700870t.s003 %2 https://acs.figshare.com/ndownloader/files/5335120 %K Dendrimeric Tectons %K DAB dendrimers %K adduct %K Halogen %K generation dendrimers %K interpenetrated sql networks %K halogen %K square topology %K synthesis %K bi %K solution %K NHC %K Crystal %K crystal lattice %K coordination properties %K supramolecular %X The use of DAB dendrimers in halogen bonding-based crystal engineering is reported. The DAB-dendr-(NHC6F4I)22 self-assembles with (E)-1,2-bis-(4-pyridyl)-ethylene in a 1:2 supramolecular adduct, whose crystal lattice is composed of 5-fold interpenetrated sql networks, which is the highest degree for a square topology reported so far. The synthesis and coordination properties of higher generation dendrimers are also described, both in the liquid state and in solution. %I ACS Publications