%0 Generic
%A Giri, Ramesh
%A Maugel, Nathan
%A Foxman, Bruce M.
%A Yu, Jin-Quan
%D 2008
%T Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex
%U https://acs.figshare.com/articles/dataset/Dehydrogenation_of_Inert_Alkyl_Groups_via_Remote_C_H_Activation_Converting_a_Propyl_Group_into_a_Allylic_Complex/2942614
%R 10.1021/om8000444.s004
%2 https://acs.figshare.com/ndownloader/files/4641355
%K Allylic
%K Inert Alkyl Groups
%K dehydrogenation
%K benzoquinone
%K stoichiometric oxidant
%K ComplexPd
%K Activation
%K alkyl group
%K Remote
%K activation
%K Propyl Group
%K allylic oxidation
%K cyclopentylcarboxamide
%K novel redox
%K sp
%K Dehydrogenation
%K Converting
%K bond
%X Pd(OAc)2-mediated dehydrogenation of an alkyl group to a double bond or a η3-allylic complex via sp3 C−H bond activation and allylic oxidation is reported. A novel redox is proposed for this double oxidation under oxidant-free conditions. A catalytic protocol using benzoquinone as the stoichiometric oxidant has also been developed for the dehydrogenation of cyclopentylcarboxamides.
%I ACS Publications