%0 Journal Article %A Sabot, Cyrille %A Bérard, Didier %A Canesi, Sylvain %D 2008 %T Expeditious Total Syntheses of Natural Allenic Products via Aromatic Ring Umpolung %U https://acs.figshare.com/articles/journal_contribution/Expeditious_Total_Syntheses_of_Natural_Allenic_Products_via_Aromatic_Ring_Umpolung/2907190 %R 10.1021/ol801921d.s001 %2 https://acs.figshare.com/ndownloader/files/4605379 %K concept %K umpolung %K diastereoselective syntheses %K Synthese %K novel oxymercuration strategy %K bromoallene moiety %K Aromatic Ring Umpolung %K panacene %K configuration %K marine %K Natural Allenic Products %K desbromopanacene %K Expeditiou %X Concise diastereoselective syntheses of the marine (±)-panacene and terrestrial (±)-desbromopanacene have been achieved in a few steps based on a concept of “aromatic ring umpolung”. The synthetic avenue to the (±)-panacene involved a novel oxymercuration strategy to produce the correct configuration of the bromoallene moiety. %I ACS Publications