%0 Journal Article %A Cline, Eric D. %A Adamson, Samantha E. %A Bernhard, Stefan %D 2008 %T Homogeneous Catalytic System for Photoinduced Hydrogen Production Utilizing Iridium and Rhodium Complexes %U https://acs.figshare.com/articles/journal_contribution/Homogeneous_Catalytic_System_for_Photoinduced_Hydrogen_Production_Utilizing_Iridium_and_Rhodium_Complexes/2899516 %R 10.1021/ic800988b.s001 %2 https://acs.figshare.com/ndownloader/files/4597657 %K photoreaction conditions %K electrochemical properties %K system poisoning %K Photoinduced Hydrogen Production Utilizing Iridium %K Rhodium ComplexesAn %K Synthetic modification %K optimized system %K photocatalytic hydrogen production %K Homogeneous Catalytic System %K Parallel screening %K electrochemical characterization %K reductive quenching pathway %K 5000 turnovers %K catalyst combinations %K CS 2 %K optimized photocatalytic system %X An efficient homogeneous catalytic system for the visible-light-induced production of hydrogen from water utilizing cyclometalated iridium(III) and tris-2,2′-bipyridyl rhodium(III) complexes is described. Synthetic modification of the photosensitizer Ir(CN)2(NN)+ and water reduction catalyst Rh(NN)33+ creates a family of catalysts with diverse photophysical and electrochemical properties. Parallel screening of the various catalyst combinations and photoreaction conditions allows the rapid development of an optimized photocatalytic system that achieves over 5000 turnovers with quantum yields (1/2 H2 per photon absorbed) greater than 34%. Photophysical and electrochemical characterization of the optimized system reveals that the reductive quenching pathway provides the necessary driving force for the formation of [Rh(NN)2]0, the active catalytic species for the reduction of water to produce hydrogen. Tests for system poisoning with mercury or CS2 provide strong evidence that the system is a true homogeneous system for photocatalytic hydrogen production. %I ACS Publications