Hatano, Bunpei Nagahashi, Keita Kijima, Tatsuro Zinc-Mediated Allylation and Alkylation of Aminals in the Presence of TMSCl and Diisopropylamine An alkylation of aminals with organozinc reagents derived from allyl bromide, benzyl bromide, α-bromoacetate, and α-bromonitrile proceeded efficiently in the presence of TMSCl and diisopropylamine. This reaction system was applied to the synthesis of an antispasmodic: butaverine. diisopropylamine;bromoacetate;presence;Alkylation;bromonitrile;Aminal;Allylation;alkylation;reaction system;Diisopropylamine;allyl bromide;benzyl bromide;aminal;TMSCl;Presence;butaverine;organozinc reagents;synthesis;antispasmodic 2008-11-21
    https://acs.figshare.com/articles/journal_contribution/Zinc_Mediated_Allylation_and_Alkylation_of_Aminals_in_the_Presence_of_TMSCl_and_Diisopropylamine/2898391
10.1021/jo8019797.s001