%0 Journal Article
%A Bellale, Eknath V.
%A Bhalerao, Dinesh S.
%A Akamanchi, Krishnacharya G.
%D 2008
%T Oxidative Conversion of α,α-Disubstituted Acetamides to Corresponding One-Carbon-Shorter Ketones Using Hypervalent Iodine (λ5) Reagents in Combination with Tetraethylammonium Bromide
%U https://acs.figshare.com/articles/journal_contribution/Oxidative_Conversion_of_Disubstituted_Acetamides_to_Corresponding_One_Carbon_Shorter_Ketones_Using_Hypervalent_Iodine_sup_5_sup_Reagents_in_Combination_with_Tetraethylammonium_Bromide/2894542
%R 10.1021/jo801580g.s001
%2 https://acs.figshare.com/ndownloader/files/4592686
%K iodine
%K oxidative dehomologation
%K Bromide
%K hypervalent
%K acid
%K TEAB
%K Combination
%K Tetraethylammonium
%K Reagent
%K Acetamide
%K method
%K solvent
%K combination
%K Disubstituted
%K reagent
%K Ketone
%K acetamide
%K Iodine
%K transformation
%K ketone
%K tetraethylammonium bromide
%K Oxidative Conversion
%K Hypervalent
%X α,α-Disubstituted acetamides undergo oxidative dehomologation to give one-carbon-shorter ketones when reacted with a hypervalent iodine (λ5) reagent in combination with tetraethylammonium bromide (TEAB) in various solvents. In further studies, one such combination of a hypervalent iodine (λ5) reagent, o-iodoxybenzoic acid, and TEAB has been established as a new, mild, efficient, and general method for the transformation.
%I ACS Publications