Barnes, David M. Barkalow, Jufang Plata, Daniel J. A Facile Method for the Preparation of MOM-Protected Carbamates A novel method for the preparation of MOM-protected carbamates is described that avoids the use of MOM-Cl, a regulated carcinogen. The two-step, one-pot procedure generates a reactive <i>N</i>-chloromethyl carbamate that is quenched with methanol to afford MOM-protected carbamates. The process is tolerant of a variety of functionalities, including Boc, sulfonamide, and acetamide protecting groups. Mild conditions for the removal of the MOM group are also described; selective deprotection of the MOM group in the presence of a Boc group has been demonstrated. carbamate;MOM group;Boc 2009-01-15
    https://acs.figshare.com/articles/journal_contribution/A_Facile_Method_for_the_Preparation_of_MOM_Protected_Carbamates/2885419
10.1021/ol8022769.s002