PQS: A New Platform for Micellar Catalysis. RCM Reactions in Water, with Catalyst Recycling
Bruce H. Lipshutz
Subir Ghorai
10.1021/ol8027829.s001
https://acs.figshare.com/articles/journal_contribution/PQS_A_New_Platform_for_Micellar_Catalysis_RCM_Reactions_in_Water_with_Catalyst_Recycling/2880910
The first “designer” surfactant containing a covalently bound ruthenium catalyst is reported. This species dissolves freely in water, forming nanomicelles in which ring-closing metathesis reactions on water-insoluble dienic substrates can occur in pure water at room temperature. It can also be recycled continuously without reaction workup.
2009-02-05 00:00:00
surfactant
metathesi
New Platform
species
room temperature
designer
ruthenium catalyst
reaction workup
Micellar Catalysis
RCM Reactions
substrate
Catalyst Recycling
dienic
PQS
nanomicelle
covalently