10.1021/ol8027829.s001
Bruce H. Lipshutz
Bruce H.
Lipshutz
Subir Ghorai
Subir
Ghorai
PQS: A New Platform for Micellar Catalysis. RCM Reactions in Water, with Catalyst Recycling
American Chemical Society
2009
surfactant
metathesi
New Platform
species
room temperature
designer
ruthenium catalyst
reaction workup
Micellar Catalysis
RCM Reactions
substrate
Catalyst Recycling
dienic
PQS
nanomicelle
covalently
2009-02-05 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/PQS_A_New_Platform_for_Micellar_Catalysis_RCM_Reactions_in_Water_with_Catalyst_Recycling/2880910
The first “designer” surfactant containing a covalently bound ruthenium catalyst is reported. This species dissolves freely in water, forming nanomicelles in which ring-closing metathesis reactions on water-insoluble dienic substrates can occur in pure water at room temperature. It can also be recycled continuously without reaction workup.