%0 Generic %A Norton, Kieran %A Kumar, G. A. %A Dilks, Jennifer L. %A Emge, Thomas J. %A Riman, Richard E. %A Brik, Mikhail G. %A Brennan, John G. %D 2009 %T Lanthanide Compounds with Fluorinated Aryloxide Ligands: Near-Infrared Emission from Nd, Tm, and Er %U https://acs.figshare.com/articles/dataset/Lanthanide_Compounds_with_Fluorinated_Aryloxide_Ligands_Near_Infrared_Emission_from_Nd_Tm_and_Er/2862703 %R 10.1021/ic8020639.s007 %2 https://acs.figshare.com/ndownloader/files/4560529 %K bond lengths %K Nd %K Emission experiments %K Tm %K isolable compounds %K chelating DME %K THF %K Lanthanide Compounds %K Fluorinated Aryloxide Ligands %K terminal phenoxide ligands %K Er %X Ln(OC6F5)3 form stable, isolable compounds with 1,2-dimethoxyethane (DME). Monomeric (DME)2Ln(OC6F5)3 (Ln = Nd, Er, Tm) adopt seven coordinate structures with two chelating DME and three terminal phenoxide ligands. Both (py)4Er(OC6F5)3 and (THF)3Yb(OC6F5)3 were also prepared and structurally characterized, with the latter being a mer-octahedral compound with bond lengths that are geometry dependent. Emission experiments on crystalline powders of the Nd(III), Tm(III), and Er(III) DME derivatives show that these compounds are highly emissive near-infrared sources. %I ACS Publications