%0 Generic
%A Norton, Kieran
%A Kumar, G. A.
%A Dilks, Jennifer L.
%A Emge, Thomas J.
%A Riman, Richard E.
%A Brik, Mikhail G.
%A Brennan, John G.
%D 2009
%T Lanthanide Compounds with Fluorinated Aryloxide Ligands: Near-Infrared Emission from Nd, Tm, and Er
%U https://acs.figshare.com/articles/dataset/Lanthanide_Compounds_with_Fluorinated_Aryloxide_Ligands_Near_Infrared_Emission_from_Nd_Tm_and_Er/2862703
%R 10.1021/ic8020639.s007
%2 https://acs.figshare.com/ndownloader/files/4560529
%K bond lengths
%K Nd
%K Emission experiments
%K Tm
%K isolable compounds
%K chelating DME
%K THF
%K Lanthanide Compounds
%K Fluorinated Aryloxide Ligands
%K terminal phenoxide ligands
%K Er
%X Ln(OC6F5)3 form stable, isolable compounds with 1,2-dimethoxyethane (DME). Monomeric (DME)2Ln(OC6F5)3 (Ln = Nd, Er, Tm) adopt seven coordinate structures with two chelating DME and three terminal phenoxide ligands. Both (py)4Er(OC6F5)3 and (THF)3Yb(OC6F5)3 were also prepared and structurally characterized, with the latter being a mer-octahedral compound with bond lengths that are geometry dependent. Emission experiments on crystalline powders of the Nd(III), Tm(III), and Er(III) DME derivatives show that these compounds are highly emissive near-infrared sources.
%I ACS Publications