Crossed Intramolecular Rauhut−Currier-Type Reactions via Dienamine Activation Eugenia Marqués-López Raquel P. Herrera Timo Marks Wiebke C. Jacobs Daniel Könning Renata M. de Figueiredo Mathias Christmann 10.1021/ol901614t.s002 https://acs.figshare.com/articles/dataset/Crossed_Intramolecular_Rauhut_Currier_Type_Reactions_via_Dienamine_Activation/2827564 The intramolecular Rauhut−Currier reaction creates a carbon−carbon bond between two tethered Michael acceptors. Previous asymmetric versions have relied on 1,4-additions of chiral nucleophilic catalysts. Herein, we investigate a novel strategy that involves the formation of electron rich dienamines as key intermediates. Our methodology provides an efficient entry to the iridoid framework. 2009-09-17 00:00:00 dienamine chiral nucleophilic catalysts intramolecular novel strategy iridoid framework Rauhut methodology version Dienamine Activation intermediate electron Crossed entry Michael acceptors Herein Intramolecular formation Previous bond