%0 Journal Article
%A Bates, Roderick W.
%A Lu, Yongna
%D 2009
%T A Formal Synthesis of Porantheridine and an Epimer
%U https://acs.figshare.com/articles/journal_contribution/A_Formal_Synthesis_of_Porantheridine_and_an_Epimer/2805592
%R 10.1021/jo9021925.s002
%2 https://acs.figshare.com/ndownloader/files/4500097
%K synthesis
%K Porantheridine
%K introduction
%K Formal Synthesis
%K cyclization
%K intermediate
%K allene
%K stereochemistry
%K method
%K porantheridine
%K choice
%K ion
%K EpimerA
%K iminium
%X A formal synthesis of porantheridine and a synthesis of its C6-epimer have been completed, employing silver-catalyzed allene cyclization to form a common cis-isoxazolidine intermediate and related N-acyl iminium ion intermediates for side-chain introduction. The stereochemistry of this step can be controlled by choice of the N-protection method.
%I ACS Publications