%0 Generic %A Zhou, Shuangliu %A Chen, Chi-Ren %A Gau, Han-Mou %D 2010 %T Highly Enantioselective 3-Furylation of Ketones Using (3-Furyl)titanium Nucleophile %U https://acs.figshare.com/articles/dataset/Highly_Enantioselective_3_Furylation_of_Ketones_Using_3_Furyl_titanium_Nucleophile/2803177 %R 10.1021/ol902454n.s003 %2 https://acs.figshare.com/ndownloader/files/4497586 %K system works %K furyl %K ketone %X A novel asymmetric 3-furyl addition of (3-furyl)Ti(OiPr)3 to ketones in the presence of 10 mol % (S)-BINOL is reported. The catalytic system works excellently for aromatic ketones, α- or β-halophenones, α,β-unsaturated ketones, and acetylfuran, affording products in high yields with excellent enantioselectivities of up to 97% ee. %I ACS Publications