10.1021/jo902081w.s001 Hai-Feng Cui Hai-Feng Cui Ying-Quan Yang Ying-Quan Yang Zhuo Chai Zhuo Chai Peng Li Peng Li Chang-Wu Zheng Chang-Wu Zheng Shi-Zheng Zhu Shi-Zheng Zhu Gang Zhao Gang Zhao Enantioselective Synthesis of Functionalized Fluorinated Cyclohexenones via Robinson Annulation Catalyzed by Primary−Secondary Diamines American Chemical Society 2010 diastereoselectivitie DiaminesPrimary diamine catalyze Robinson Annulation Catalyzed quaternary chiral center chiral cyclohexenones Functionalized Fluorinated Cyclohexenones catalyst Robinson annulation stereogenic centers Primary yield Enantioselective Synthesis enantioselectivitie 2010-01-01 00:00:00 Dataset https://acs.figshare.com/articles/dataset/Enantioselective_Synthesis_of_Functionalized_Fluorinated_Cyclohexenones_via_Robinson_Annulation_Catalyzed_by_Primary_Secondary_Diamines/2803000 Primary−secondary diamine catalysts were used to catalyze the asymmetric Robinson annulation to synthesize multiply substituted fluorinated chiral cyclohexenones with two contiguous stereogenic centers, one of which is a fluorinated quaternary chiral center, with excellent enantioselectivities and diastereoselectivities in moderate to good yields.