%0 Generic
%A Redondo, María C.
%A Ribagorda, María
%A Carreño, M. Carmen
%D 2010
%T Exploring Morita−Baylis−Hillman Reactions of p-Quinols
%U https://acs.figshare.com/articles/dataset/Exploring_Morita_Baylis_Hillman_Reactions_of_i_p_i_Quinols/2794312
%R 10.1021/ol902763g.s001
%2 https://acs.figshare.com/ndownloader/files/4488676
%K reaction conditions
%K chemical yields
%K autocatalytic mechanism
%K Morita
%X The Morita−Baylis−Hillman reaction of p-methylquinols with activated aromatic aldehydes has been studied. Depending on the reaction conditions (solvent and additives), three different products were formed. A mono or double Morita−Baylis−Hillman adduct and a fused 1,3-dioxolane could be obtained in good chemical yields. The use of non-nucleophilic bases to promote the reaction suggested an autocatalytic mechanism.
%I ACS Publications