10.1021/ic902450c.s002
Jiyong Hu
Jiyong
Hu
Jin’an Zhao
Jin’an
Zhao
Qianqian Guo
Qianqian
Guo
Hongwei Hou
Hongwei
Hou
Yaoting Fan
Yaoting
Fan
Construction of a Ag<sub>12</sub> High-Nuclearity Metallamacrocyclic 3D Framework
American Chemical Society
2010
silver ions
10 K
Ag
dodecanuclear silver building blocks
phosphorescence emission
2010-04-19 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Construction_of_a_Ag_sub_12_sub_High_Nuclearity_Metallamacrocyclic_3D_Framework/2775904
An unprecedented high-nuclearity metallamacrocycle-based 3D silver framework with formula {[Ag<sub>2</sub>(C<sub>25</sub>H<sub>27</sub>N<sub>6</sub>O)<sub>2</sub>](CH<sub>3</sub>OH)(H<sub>2</sub>O)<sub>0.17</sub>}<sub><i>n</i></sub> (<b>1</b>), built on the basis of dodecanuclear silver building blocks, has been synthesized and characterized, and it shows strong phosphorescence emission at 10 K, which is a consequence of the presence of intersystem crossing from singlet to triplet caused by the heavy-atom effect of silver ions.