Wang, Chih-Min Lin, Chia-Hui Yang, Ciao-Wei Lii, Kwang-Hwa Zinc Germanates Incorporating Organic Amine Ligands: Solvothermal Synthesis and Structural Characterization of Zn<sub>2</sub>Ge<sub>4</sub>O<sub>10</sub>(NH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>NH<sub>2</sub>) and ZnGe<sub>2</sub>O<sub>5</sub>(NH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>NH<sub>2</sub>) Two zinc germanates incorporating bidentate-bridging organic amine ligands have been synthesized under solvothermal conditions by using the amines as solvents. Their structural features are infinite chains formed of edge-sharing ZnO<sub>4</sub>N trigonal bipyramids and unbranched vierer single layers with the composition [Ge<sub>4</sub>O<sub>10</sub>] and discrete ZnO<sub>2</sub>N<sub>2</sub> tetrahedra and unbranched zweier double chains with the composition [Ge<sub>2</sub>O<sub>5</sub>], respectively. Ge 2O;solvent;Structural Characterization;Solvothermal Synthesis;ZnGe 2O zinc germanates;unbranched zweier;amines;bipyramid;solvothermal conditions;Zn 2Ge;Zinc Germanates Incorporating Organic Amine Ligands;4N;Ge 4O;amine ligands;ZnO 2N tetrahedra;unbranched vierer 2010-07-05
    https://acs.figshare.com/articles/journal_contribution/Zinc_Germanates_Incorporating_Organic_Amine_Ligands_Solvothermal_Synthesis_and_Structural_Characterization_of_Zn_sub_2_sub_Ge_sub_4_sub_O_sub_10_sub_NH_sub_2_sub_CH_sub_2_sub_CH_sub_2_sub_CH_sub_2_sub_NH_sub_2_sub_and_ZnGe_sub_2_sub_O_sub_5_sub_NH_sub_2_s/2755708
10.1021/ic1004825.s001