10.1021/cg100831c.s002
Oksana Danylyuk
Oksana
Danylyuk
Barbara Leśniewska
Barbara
Leśniewska
Kinga Suwinska
Kinga
Suwinska
Nabila Matoussi
Nabila
Matoussi
Anthony W. Coleman
Anthony W.
Coleman
Structural Diversity in the Crystalline Complexes of <i>para</i>-Sulfonato-calix[4]arene with Bipyridinium Derivatives
American Chemical Society
2010
BPE
bipyridinium derivatives
BPP
BP
noncovalent interactions
Bipyridinium DerivativesThe
Structural Diversity
C 4S
Crystalline Complexes
complexes show
2010-10-06 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Structural_Diversity_in_the_Crystalline_Complexes_of_i_para_i_Sulfonato_calix_4_arene_with_Bipyridinium_Derivatives/2723797
The solid-state structures of eight complexes between <i>para</i>-sulfonato-calix[4]arene (<b>C4S</b>) and bipyridinium derivatives, 4,4′-bipyridine (<b>BP</b>), 1,2-bis(4-pyridyl)ethane (<b>BPE</b>), and 1,3-bis(4-pyridyl)propane (<b>BPP</b>), have been determined. All the complexes show high degrees of solvation, involving water and ethanol or methanol or acetone. The observed host/guest stoichiometry is determined in part by the nature of the solvent. A wide range of noncovalent interactions are observed in the various complexes, with the dominant interaction being hydrogen bonding and aromatic−aromatic stacking.