A Novel Fluorinated Gold(I) N-Heterocyclic Carbene Complex: Exploiting Fluorine Stereoelectronic Effects To Control Molecular Topology Susann Paul W. Bernd Schweizer Marc-Olivier Ebert Ryan Gilmour 10.1021/om100789n.s002 https://acs.figshare.com/articles/dataset/A_Novel_Fluorinated_Gold_I_N_Heterocyclic_Carbene_Complex_Exploiting_Fluorine_Stereoelectronic_Effects_To_Control_Molecular_Topology/2719678 The synthesis of a novel fluorinated Au(I) N-heterocyclic carbene is disclosed together with solid-state and solution-phase conformational analysis. The potential of the fluorine gauche effect [σ<sub>C−H</sub> → σ*<sub>C−F</sub>] for controlling the topology of catalytically relevant architectures is showcased by a representative NHC in which the C−F bond is β to the triazolium moiety. 2010-10-25 00:00:00 Control Molecular TopologyThe synthesis fluorine showcased Fluorinated Carbene representative NHC carbene catalytically topology triazolium moiety analysis Exploiting Fluorine Stereoelectronic Effects Complex bond