10.1021/om100789n.s002
Susann Paul
Susann
Paul
W. Bernd Schweizer
W. Bernd
Schweizer
Marc-Olivier Ebert
Marc-Olivier
Ebert
Ryan Gilmour
Ryan
Gilmour
A Novel Fluorinated Gold(I) N-Heterocyclic Carbene Complex: Exploiting Fluorine Stereoelectronic Effects To Control Molecular Topology
American Chemical Society
2010
Control Molecular TopologyThe synthesis
fluorine
showcased
Fluorinated
Carbene
representative NHC
carbene
catalytically
topology
triazolium moiety
analysis
Exploiting Fluorine Stereoelectronic Effects
Complex
bond
2010-10-25 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/A_Novel_Fluorinated_Gold_I_N_Heterocyclic_Carbene_Complex_Exploiting_Fluorine_Stereoelectronic_Effects_To_Control_Molecular_Topology/2719678
The synthesis of a novel fluorinated Au(I) N-heterocyclic carbene is disclosed together with solid-state and solution-phase conformational analysis. The potential of the fluorine gauche effect [σ<sub>C−H</sub> → σ*<sub>C−F</sub>] for controlling the topology of catalytically relevant architectures is showcased by a representative NHC in which the C−F bond is β to the triazolium moiety.