10.1021/om100789n.s002 Susann Paul Susann Paul W. Bernd Schweizer W. Bernd Schweizer Marc-Olivier Ebert Marc-Olivier Ebert Ryan Gilmour Ryan Gilmour A Novel Fluorinated Gold(I) N-Heterocyclic Carbene Complex: Exploiting Fluorine Stereoelectronic Effects To Control Molecular Topology American Chemical Society 2010 Control Molecular TopologyThe synthesis fluorine showcased Fluorinated Carbene representative NHC carbene catalytically topology triazolium moiety analysis Exploiting Fluorine Stereoelectronic Effects Complex bond 2010-10-25 00:00:00 Dataset https://acs.figshare.com/articles/dataset/A_Novel_Fluorinated_Gold_I_N_Heterocyclic_Carbene_Complex_Exploiting_Fluorine_Stereoelectronic_Effects_To_Control_Molecular_Topology/2719678 The synthesis of a novel fluorinated Au(I) N-heterocyclic carbene is disclosed together with solid-state and solution-phase conformational analysis. The potential of the fluorine gauche effect [σ<sub>C−H</sub> → σ*<sub>C−F</sub>] for controlling the topology of catalytically relevant architectures is showcased by a representative NHC in which the C−F bond is β to the triazolium moiety.