%0 Journal Article %A Nemoto, Tetsuhiro %A Ishige, Yuta %A Yoshida, Mariko %A Kohno, Yuta %A Kanematsu, Mutsumi %A Hamada, Yasumasa %D 2010 %T Novel Method for Synthesizing Spiro[4.5]cyclohexadienones through a Pd-Catalyzed Intramolecular ipso-Friedel−Crafts Allylic Alkylation of Phenols %U https://acs.figshare.com/articles/journal_contribution/Novel_Method_for_Synthesizing_Spiro_4_5_cyclohexadienones_through_a_Pd_Catalyzed_Intramolecular_i_ipso_i_Friedel_Crafts_Allylic_Alkylation_of_Phenols/2716369 %R 10.1021/ol102190s.s002 %2 https://acs.figshare.com/ndownloader/files/4392319 %K Spiro %K Allylic %K intramolecular %K Phenol %K Alkylation %K spirocenter %K allylic %K access %K Novel Method %K phenol %K method %K alkylation %K spiro %K Intramolecular %K quaternary %K enantioselective construction %K Synthesizing %X The first successful Pd-catalyzed intramolecular ipso-Friedel−Crafts allylic alkylation of phenols, which provided a new access to spiro[4.5]cyclohexadienones, is described. The present method could be applied to catalytic enantioselective construction of an all-carbon quaternary spirocenter. %I ACS Publications