10.1021/ol102190s.s002
Tetsuhiro Nemoto
Tetsuhiro
Nemoto
Yuta Ishige
Yuta
Ishige
Mariko Yoshida
Mariko
Yoshida
Yuta Kohno
Yuta
Kohno
Mutsumi Kanematsu
Mutsumi
Kanematsu
Yasumasa Hamada
Yasumasa
Hamada
Novel Method for Synthesizing Spiro[4.5]cyclohexadienones through a Pd-Catalyzed Intramolecular <i>ipso</i>-Friedel−Crafts Allylic Alkylation of Phenols
American Chemical Society
2010
Spiro
Allylic
intramolecular
Phenol
Alkylation
spirocenter
allylic
access
Novel Method
phenol
method
alkylation
spiro
Intramolecular
quaternary
enantioselective construction
Synthesizing
2010-11-05 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Novel_Method_for_Synthesizing_Spiro_4_5_cyclohexadienones_through_a_Pd_Catalyzed_Intramolecular_i_ipso_i_Friedel_Crafts_Allylic_Alkylation_of_Phenols/2716369
The first successful Pd-catalyzed intramolecular <i>ipso</i>-Friedel−Crafts allylic alkylation of phenols, which provided a new access to spiro[4.5]cyclohexadienones, is described. The present method could be applied to catalytic enantioselective construction of an all-carbon quaternary spirocenter.