%0 Journal Article
%A Alberding, Brian G.
%A Chisholm, Malcolm H.
%A Gustafson, Terry L.
%A Liu, Yao
%A Reed, Carly R.
%A Turro, Claudia
%D 2010
%T Photophysical Studies of trans-Bis(phenylethynyldiisopropylamidinato)bis(acetato)dimetal Complexes Involving MM Quadruple Bonds Where M = Mo or W
%U https://acs.figshare.com/articles/journal_contribution/Photophysical_Studies_of_i_trans_i_Bis_phenylethynyldiisopropylamidinato_bis_acetato_dimetal_Complexes_Involving_MM_Quadruple_Bonds_Where_M_Mo_or_W/2706277
%R 10.1021/jp108544v.s001
%2 https://acs.figshare.com/ndownloader/files/4382224
%K T 1 states
%K II T 1
%K absorption
%K MM Quadruple Bonds
%K S 1 states
%K S 1
%K Mo
%K emission
%K compound
%K 1 MLCT
%K T 1 state
%X The title compounds trans-M2(O2CMe)2[C(iPrN)2CCPh]2, I (M = Mo) and II (M = W), show electronic absorptions in the visible region of the spectrum assignable to 1MLCT [M2δ to phenylethynylamidinate π*]. These compounds show dual emission from S1 and T1 states. For both I and II, S1 is 1MLCT, but for I the T1 state is shown to be MMδδ* while for II T1 is 3MLCT. The lifetimes of the S1 and T1 states have been determined by femtosecond and nanosecond transient absorption spectroscopy: for I S1 ∼ 20 ps and T1 ∼ 100 μs and for II S1 ∼ 6 ps and T1 ∼ 5 μs. From solvent dependence of the absorption and emission spectra, we suggest that the S1 states are localized on one amidinate ligand though the initial absorption is to a delocalized state.
%I ACS Publications