Chen, Ziyi Luo, Daibing Kang, Maoping Lin, Zhien New Semiconducting Coordination Polymers from Zinc Sulfide Clusters and Chains Two new semiconducting zinc coordination polymers, Zn<sub>8</sub>S(SPh)<sub>14</sub>(bpy) (<b>1</b>) and Zn<sub>2</sub>(SPh)<sub>4</sub>(bpy) (<b>2</b>), have been synthesized by a dual-ligand approach. Single-crystal structural analyses indicate that compound <b>1</b> has a helical-chain structure with P1 clusters bridging with bipyridyl (bpy) ligands and compound <b>2</b> possesses a layered structure with zinc sulfide chains cross-linked with bpy ligands. The diffuse-reflectance spectra reveal that the band gaps of the two compounds are 2.41 eV for <b>1</b> and 2.56 eV for <b>2</b>. bpy ligands;2.41 eV;compound 1;compound 2;semiconducting zinc coordination polymers;New Semiconducting Coordination Polymers;P 1 clusters;Zinc Sulfide Clusters;2.56 eV;Zn;band gaps;8S 2011-06-06
    https://acs.figshare.com/articles/journal_contribution/New_Semiconducting_Coordination_Polymers_from_Zinc_Sulfide_Clusters_and_Chains/2644642
10.1021/ic2004003.s003