Lian, Yajing M. L. Davies, Huw Combined C–H Functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction Vinyl ethers selectively undergo the combined C–H functionalization/Cope rearrangement reaction via an s-cis/boat transition state. With chiral dirhodium catalysts, products are generated in a highly diastereoselective and enantioselective fashion. This reaction can be considered as a surrogate to the traditional vinylogous Mukaiyama aldol reaction. Effective kinetic resolution has been achieved, leading to the recovery of a cyclic vinyl ether with axial chirality of high enantiomeric purity. chiral dirhodium catalysts;enantiomeric purity;Vinylogous Mukaiyama Aldol ReactionVinyl ethers;cyclic vinyl ether;vinylogous Mukaiyama aldol reaction;enantioselective fashion;Vinyl Ethers 2011-08-10
    https://acs.figshare.com/articles/dataset/Combined_C_H_Functionalization_Cope_Rearrangement_with_Vinyl_Ethers_as_a_Surrogate_for_the_Vinylogous_Mukaiyama_Aldol_Reaction/2624518
10.1021/ja2051155.s002