Luo, Wei Zakharov, Lev N. Liu, Shih-Yuan 1,2-BN Cyclohexane: Synthesis, Structure, Dynamics, and Reactivity BN/CC isosterism has emerged as a viable strategy to increase the structural diversity of carbon-based compounds. We present the first synthesis and characterization of the parent 1,2-BN cyclohexane, the BN-isostere of cyclohexane. 1,2-BN cyclohexane is an air- and water-stable compound that cleanly forms a trimer with release of dihydrogen when thermally activated. We also demonstrate that 1,2-BN cyclohexane has a lower activation barrier for ring inversion than cyclohexane due to BN/CC isosterism. BN;isosterism;activation barrier;cyclohexane;compound;ring inversion 2011-08-24
    https://acs.figshare.com/articles/dataset/1_2_BN_Cyclohexane_Synthesis_Structure_Dynamics_and_Reactivity/2621294
10.1021/ja206497x.s005