10.1021/ol201696y.s001 Yolanda Arroyo Yolanda Arroyo M. Ascensión Sanz-Tejedor M. Ascensión Sanz-Tejedor Inés Alonso Inés Alonso José L. García-Ruano José L. García-Ruano Synthesis of Optically Pure <i>vic</i>-Sulfanyl Amines Mediated by a Remote Sulfinyl Group American Chemical Society 2011 Li Mediated Pure stereochemical results Optically PMP CPCM model desulfinylation benzylcarbanion derivative Gaussian 09 program Synthesi Remote Sulfinyl GroupEnantiomerically DFT mPW 1PW level syn stereoselective manner Theoretical studies aldimine Amine 2011-09-02 00:00:00 Dataset https://acs.figshare.com/articles/dataset/Synthesis_of_Optically_Pure_i_vic_i_Sulfanyl_Amines_Mediated_by_a_Remote_Sulfinyl_Group/2618269 Enantiomerically pure <i>syn</i>-1,2-diaryl-1,2-sulfanylamine derivatives can be obtained in a completely stereoselective manner by reaction of the benzylcarbanion Li-(<i>S</i>)-<b>1</b> with <i>N</i>-phenyl (or PMP)-arylidene aldimines and further desulfinylation with <i>t</i>-BuLi. Theoretical studies at the DFT (mPW1PW91) level with the CPCM model, by using the Gaussian09 program, provide a good explanation for the stereochemical results.