10.1021/ol2016516.s002
Lukas Zöphel
Lukas
Zöphel
Volker Enkelmann
Volker
Enkelmann
Ralph Rieger
Ralph
Rieger
Klaus Müllen
Klaus
Müllen
Saddle Shaped Hexaaryl[<i>a,c,fg,j,l,op</i>]tetracenes from 4,5,9,10-Tetrafunctionalized Pyrenes
American Chemical Society
2011
PyrenesA
Electronic properties
functionalized
Hexaaryl
Stille
building block
crystal structures
synthesis
cyclodehydrogenation
pyrene
saddle conformation
hexaarylated tetracenes
Tetrafunctionalized
2011-09-02 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Saddle_Shaped_Hexaaryl_i_a_c_fg_j_l_op_i_tetracenes_from_4_5_9_10_Tetrafunctionalized_Pyrenes/2618224
A new K-region functionalized pyrene is presented which was used as a building block for the straightforward synthesis of hexaaryl[<i>a,c,fg,j,l,op</i>]tetracene via fourfold Stille coupling and subsequent cyclodehydrogenation. Electronic properties and crystal structures are provided and reveal a saddle conformation for the curved hexaarylated tetracenes.