%0 Generic
%A Wehmschulte, Rudolf J.
%A Wojtas, Lukasz
%D 2011
%T Cationic Ethylzinc Compound:
A Benzene Complex with
Catalytic Activity in Hydroamination and Hydrosilylation Reactions
%U https://acs.figshare.com/articles/dataset/Cationic_Ethylzinc_Compound_A_Benzene_Complex_with_Catalytic_Activity_in_Hydroamination_and_Hydrosilylation_Reactions/2581744
%R 10.1021/ic201921d.s002
%2 https://acs.figshare.com/ndownloader/files/4227529
%K ethene elimination
%K Hydroamination
%K amine adduct
%K Et 2Zn
%K CH
%K Ph 3C
%K Catalytic Activity
%K hydrosilylation
%K Cationic Ethylzinc
%K Hydrosilylation ReactionsThe
%K abstraction
%K trityl salt
%K hydroamination experiment
%K ionlike species
%K ion pair
%K transition
%K 6H
%K EtZn
%K intramolecular hydroamination reactions
%K Benzene Complex
%K bond
%K 2CHCH
%X The tight ion pair [EtZn(η3-C6H6)][CHB11Cl11]·C6H6 (1·C6H6) was
obtained
through β-hydrogen abstraction and concomitant ethene elimination
from Et2Zn with the trityl salt [Ph3C][CHB11Cl11]. This ionlike species shows catalytic activity
in hydrosilylation and intramolecular hydroamination reactions. The
amine adduct {CH2CHCH2C(Ph2)CH2NH2}3ZnCB11Cl11 (3), which features a rare transition metal–carborane
σ bond, was isolated from a hydroamination experiment.
%I ACS Publications