%0 Journal Article
%A Momčilović, Nebojša
%A Clark, Paul G.
%A Boydston, Andrew J.
%A Grubbs, Robert H.
%D 2011
%T One-Pot Synthesis of Polyrotaxanes via Acyclic Diene Metathesis Polymerization of Supramolecular Monomers
%U https://acs.figshare.com/articles/journal_contribution/One_Pot_Synthesis_of_Polyrotaxanes_via_Acyclic_Diene_Metathesis_Polymerization_of_Supramolecular_Monomers/2578840
%R 10.1021/ja208515r.s001
%2 https://acs.figshare.com/ndownloader/files/4222927
%K polymerizable ammonium salt
%K Polyrotaxane
%K complexed
%K crown ether
%K ADMet polymerization
%K 19.3 kDa
%K polyrotaxane
%K method
%K synthesis
%K combination
%K Mw
%K complexation
%K supramolecular monomer
%K MonomersA
%K Supramolecular
%K Acyclic Diene Metathesis Polymerization
%K Synthesi
%X A one-pot synthesis of polyrotaxanes has been developed. The method employs a supramolecular monomer comprising a polymerizable ammonium salt and crown ether, in combination with dynamic ADMet polymerization. Ultimately, highly efficient complexation, polymerization, and end-capping were accomplished in a single operation to yield polyrotaxanes with Mw up to 19.3 kDa and >80% of the repeat units being complexed.
%I ACS Publications