%0 Journal Article %A Momčilović, Nebojša %A Clark, Paul G. %A Boydston, Andrew J. %A Grubbs, Robert H. %D 2011 %T One-Pot Synthesis of Polyrotaxanes via Acyclic Diene Metathesis Polymerization of Supramolecular Monomers %U https://acs.figshare.com/articles/journal_contribution/One_Pot_Synthesis_of_Polyrotaxanes_via_Acyclic_Diene_Metathesis_Polymerization_of_Supramolecular_Monomers/2578840 %R 10.1021/ja208515r.s001 %2 https://acs.figshare.com/ndownloader/files/4222927 %K polymerizable ammonium salt %K Polyrotaxane %K complexed %K crown ether %K ADMet polymerization %K 19.3 kDa %K polyrotaxane %K method %K synthesis %K combination %K Mw %K complexation %K supramolecular monomer %K MonomersA %K Supramolecular %K Acyclic Diene Metathesis Polymerization %K Synthesi %X A one-pot synthesis of polyrotaxanes has been developed. The method employs a supramolecular monomer comprising a polymerizable ammonium salt and crown ether, in combination with dynamic ADMet polymerization. Ultimately, highly efficient complexation, polymerization, and end-capping were accomplished in a single operation to yield polyrotaxanes with Mw up to 19.3 kDa and >80% of the repeat units being complexed. %I ACS Publications