10.1021/ja208515r.s001 Nebojša Momčilović Nebojša Momčilović Paul G. Clark Paul G. Clark Andrew J. Boydston Andrew J. Boydston Robert H. Grubbs Robert H. Grubbs One-Pot Synthesis of Polyrotaxanes via Acyclic Diene Metathesis Polymerization of Supramolecular Monomers American Chemical Society 2011 polymerizable ammonium salt Polyrotaxane complexed crown ether ADMet polymerization 19.3 kDa polyrotaxane method synthesis combination Mw complexation supramolecular monomer MonomersA Supramolecular Acyclic Diene Metathesis Polymerization Synthesi 2011-11-30 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/One_Pot_Synthesis_of_Polyrotaxanes_via_Acyclic_Diene_Metathesis_Polymerization_of_Supramolecular_Monomers/2578840 A one-pot synthesis of polyrotaxanes has been developed. The method employs a supramolecular monomer comprising a polymerizable ammonium salt and crown ether, in combination with dynamic ADMet polymerization. Ultimately, highly efficient complexation, polymerization, and end-capping were accomplished in a single operation to yield polyrotaxanes with <i>M</i><sub>w</sub> up to 19.3 kDa and >80% of the repeat units being complexed.