10.1021/om300387q.s002 Elumalai Kumaran Elumalai Kumaran Weng Kee Leong Weng Kee Leong The Reaction of [Cp*RhCl<sub>2</sub>]<sub>2</sub>, Aniline, and a Terminal Alkyne: Formation of Cyclometalated Rhodium(III) Complexes American Chemical Society 2016 RCCH reaction pathway Terminal Alkyne terminal alkyne Cp 2016-02-20 17:39:16 Dataset https://acs.figshare.com/articles/dataset/The_Reaction_of_Cp_RhCl_sub_2_sub_sub_2_sub_Aniline_and_a_Terminal_Alkyne_Formation_of_Cyclometalated_Rhodium_III_Complexes/2506906 The reaction of [Cp*RhCl<sub>2</sub>]<sub>2</sub> with an aniline (R′NH<sub>2</sub>) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh­(Cl)­[N­(R′)C­(CH<sub>2</sub>R)­CHCR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.