Pinto de Magalhães, Halua Lüthi, Hans Peter Togni, Antonio Reductive Eliminations from λ<sup>3</sup>-Iodanes: Understanding Selectivity and the Crucial Role of the Hypervalent Bond This computational study investigates the factors governing the selectivity of the reductive eliminations from rapidly equilibrating isomeric λ<sup>3</sup>-iodanes derived from a diaryl iodonium salt and a nucleophile. The chemoselectivity is mainly determined by the partial charge at the ipso-carbon atom involved in the 3-center–4-electron bond. Crucial Role;Reductive Eliminations;selectivity;chemoselectivity;isomeric;iodane;Hypervalent BondThis;charge;factor;diaryl iodonium salt;nucleophile;center;equilibrating;Selectivity;reductive eliminations;Iodane;bond 2012-08-03
    https://acs.figshare.com/articles/journal_contribution/Reductive_Eliminations_from_sup_3_sup_Iodanes_Understanding_Selectivity_and_the_Crucial_Role_of_the_Hypervalent_Bond/2499598
10.1021/ol3014039.s001