%0 Generic
%A Wang, Yi-Ming
%A Wu, Jeffrey
%A Hoong, Christina
%A Rauniyar, Vivek
%A Toste, F. Dean
%D 2012
%T Enantioselective Halocyclization
Using Reagents Tailored
for Chiral Anion Phase-Transfer Catalysis
%U https://acs.figshare.com/articles/dataset/Enantioselective_Halocyclization_Using_Reagents_Tailored_for_Chiral_Anion_Phase_Transfer_Catalysis/2497975
%R 10.1021/ja305795x.s004
%2 https://acs.figshare.com/ndownloader/files/4140850
%K electrophilic bromine
%K application
%K enantioselectivity
%K iodine sources
%K Reagents Tailored
%K Enantioselective Halocyclization
%K CatalysisA
%K Anion
%K Chiral
%K enantioselective halogenation
%K reagent
%K anion
%K chiral
%X A chiral anion phase-transfer system for enantioselective
halogenation
is described. Highly insoluble, ionic reagents were developed as electrophilic
bromine and iodine sources, and application of this system to o-anilidostyrenes afforded halogenated 4H-3,1-benzoxazines with excellent yield and enantioselectivity.
%I ACS Publications