Stepwise Photocatalytic Dissociation of Methanol and Water on TiO<sub>2</sub>(110) GuoQing XuChenbiao RenZefeng YangWenshao MaZhibo DaiDongxu FanHongjun MintonTimothy K. YangXueming 2012 We have investigated the photocatalysis of partially deuterated methanol (CD<sub>3</sub>OH) and H<sub>2</sub>O on TiO<sub>2</sub>(110) at 400 nm using a newly developed photocatalysis apparatus in combination with theoretical calculations. Photocatalyzed products, CD<sub>2</sub>O on Ti<sub>5c</sub> sites, and H and D atoms on bridge-bonded oxygen (BBO) sites from CD<sub>3</sub>OH have been clearly detected, while no evidence of H<sub>2</sub>O photocatalysis was found. The experimental results show that dissociation of CD<sub>3</sub>OH on TiO<sub>2</sub>(110) occurs in a stepwise manner in which the O–H dissociation proceeds first and is then followed by C–D dissociation. Theoretical calculations indicate that the high reverse barrier to C–D recombination and the facile desorption of CD<sub>2</sub>O make photocatalytic methanol dissociation on TiO<sub>2</sub>(110) proceed efficiently. Theoretical results also reveal that the reverse reactions, i.e, O–H recombination after H<sub>2</sub>O photocatalytic dissociation on TiO<sub>2</sub>(110), may occur easily, thus inhibiting efficient photocatalytic water splitting.