10.1021/es302651q.s001 Quanpeng Chen Quanpeng Chen Jinhua Li Jinhua Li Xuejin Li Xuejin Li Ke Huang Ke Huang Baoxue Zhou Baoxue Zhou Weimin Cai Weimin Cai Wenfeng Shangguan Wenfeng Shangguan Visible-Light Responsive Photocatalytic Fuel Cell Based on WO<sub>3</sub>/W Photoanode and Cu<sub>2</sub>O/Cu Photocathode for Simultaneous Wastewater Treatment and Electricity Generation American Chemical Society 2012 WO 5 h operation Simultaneous Wastewater Treatment electron compound photocatalytic fuel cell PFC system Cu 2O Photocathode Cu 2O photocathode photoanode VNHE electricity generation 2012-10-16 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/Visible_Light_Responsive_Photocatalytic_Fuel_Cell_Based_on_WO_sub_3_sub_W_Photoanode_and_Cu_sub_2_sub_O_Cu_Photocathode_for_Simultaneous_Wastewater_Treatment_and_Electricity_Generation/2477956 A visible-light driven photocatalytic fuel cell (PFC) system comprised of WO<sub>3</sub>/W photoanode and Cu<sub>2</sub>O/Cu photocathode was established for organic compounds degradation with simultaneous electricity generation. The central idea for its operation is the mismatched Fermi levels between the two photoelectrodes. Under light illumination, the Fermi level of WO<sub>3</sub>/W photoanode is higher than that of Cu<sub>2</sub>O/Cu photocathode. An interior bias can be produced based on which the electrons of WO<sub>3</sub>/W photoanode can transfer from the external circuit to combine with the holes of Cu<sub>2</sub>O/Cu photocathode then generates the electricity. In this manner, the electron/hole pairs separations at two photoelectrodes are facilitated to release the holes of WO<sub>3</sub>/W photoanode and electrons of Cu<sub>2</sub>O/Cu photocathode. Organic compounds can be decomposed by the holes of WO<sub>3</sub>/W photoanode due to its high oxidation power (+3.1–3.2 <i>V</i><sub>NHE</sub>). The results demonstrated that various model compounds including phenol, Rhodamine B, and Congo red can be successfully decomposed in this PFC system, with the degradation rate after 5 h operation were obtained to be 58%, 63%, and 74%, respectively. The consistent operation for continuous water treatment with the electricity generation at a long time scale was also confirmed from the result. The proposed PFC system provides a self-sustained and energy-saving way for simultaneous wastewater treatment and energy recovery.