10.1021/cg300971r.s001
Benlai Wu
Benlai
Wu
Song Wang
Song
Wang
Ruiying Wang
Ruiying
Wang
Jinxia Xu
Jinxia
Xu
Daqiang Yuan
Daqiang
Yuan
Hongwei Hou
Hongwei
Hou
Chiral Metallocycles Templated
Novel Chiral Water
Frameworks
American Chemical Society
2013
HL
dinuclear metallocyclic complexes
monoanionic form
metal centers
chiral ligand coordinates
chiral NiII complexes
H 2L
anchor chiral water chains
bichelating antiparallel fashion
chiral 3 D supermolecule
1 D channels
nanometer cages
Chiral Metallocycles Templated Novel Chiral Water FrameworksAn
2013-02-06 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Chiral_Metallocycles_Templated_Novel_Chiral_Water_Frameworks/2445757
An intentionally synthesized chiral terpyridyl ligand <i>S</i>-2(4-(2,6-di(pyridin-2-yl)pyridin-4-yl)-benzylamino)propanoic
acid
(H<sub>2</sub>L) was used to construct two chiral Ni<sup>II</sup> complexes,
[Ni<sub>2</sub>(HL)<sub>2</sub>(N<sub>3</sub>)(H<sub>2</sub>O)](N<sub>3</sub>)·19H<sub>2</sub>O (<b>1</b>) and [Ni<sub>2</sub>(HL)<sub>2</sub>(N<sub>3</sub>)<sub>2</sub>]·7H<sub>2</sub>O (<b>2</b>). Both complexes are
dinuclear metallocyclic complexes. The monoanionic form (HL)<sup>−</sup> of the chiral ligand coordinates to the metal centers in a bichelating
antiparallel fashion to form the metallomacrocycles where the chiral
metallocycles Ni<sub>2</sub>(HL)<sub>2</sub> template the formation
of a novel chiral 3D zeolite-like water framework with nanometer cages
trapping the metallocycles or anchor chiral water chains in the 1D
channels of a resulting chiral 3D supermolecule, respectively.