10.1021/ol303469a.s001
Richard G. Cornwall
Richard G.
Cornwall
Baoguo Zhao
Baoguo
Zhao
Yian Shi
Yian
Shi
Catalytic Asymmetric Synthesis of Cyclic Sulfamides from Conjugated Dienes
American Chemical Society
2013
presence
ee
Pd
cyclic sulfamides
alkyl dienes
dioxide
Conjugated DienesThis paper
Catalytic Asymmetric Synthesis
chiral phosphoramidite ligand
gram scale
Cyclic Sulfamides
diamination
2013-02-15 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Catalytic_Asymmetric_Synthesis_of_Cyclic_Sulfamides_from_Conjugated_Dienes/2442952
This paper describes the catalytic asymmetric diamination of alkyl dienes using <i>N</i>,<i>N</i>′-di-<i>tert</i>-butylthiadiaziridine 1,1-dioxide in the presence of Pd(0) and a chiral phosphoramidite ligand to give cyclic sulfamides in high yield and high ee. The diamination is also amenable to gram scale.