10.1021/jp311912b.s001 Ramses Snoeckx Ramses Snoeckx Robby Aerts Robby Aerts Xin Tu Xin Tu Annemie Bogaerts Annemie Bogaerts Plasma-Based Dry Reforming: A Computational Study Ranging from the Nanoseconds to Seconds Time Scale American Chemical Society 2016 pulse DBD dielectric barrier discharge CH 4 conversion Seconds Time ScaleWe chemical microdischarge dielectric barrier discharge reactor CO 2 plasma filamentary discharge regime 2016-02-19 18:06:19 Journal contribution https://acs.figshare.com/articles/journal_contribution/Plasma_Based_Dry_Reforming_A_Computational_Study_Ranging_from_the_Nanoseconds_to_Seconds_Time_Scale/2434510 We present a computational study for the conversion of CH<sub>4</sub> and CO<sub>2</sub> into value-added chemicals, i.e., the so-called “dry reforming of methane”, in a dielectric barrier discharge reactor. A zero-dimensional chemical kinetics model is applied to study the plasma chemistry in a 1:1 CH<sub>4</sub>/CO<sub>2</sub> mixture. The calculations are first performed for one microdischarge pulse and its afterglow, to study in detail the chemical pathways of the conversion. Subsequently, long time-scale simulations are carried out, corresponding to real residence times in the plasma, assuming a large number of consecutive microdischarge pulses, to mimic the conditions of the filamentary discharge regime in a dielectric barrier discharge (DBD) reactor. The conversion of CH<sub>4</sub> and CO<sub>2</sub> as well as the selectivity of the formed products and the energy cost and energy efficiency of the process are calculated and compared to experiments for a range of different powers and gas flows, and reasonable agreement is reached.