%0 Generic %A Kelly, Michael J. %A Broomsgrove, Alexander E.J. %A Morgan, Ian R. %A Siewert, Inke %A Fitzpatrick, Philip %A Smart, Jessica %A Vidovic, Dragoslav %A Aldridge, Simon %D 2013 %T Syntheses and Anion Binding Capabilities of Bis(diarylboryl) Ferrocenes and Related Systems %U https://acs.figshare.com/articles/dataset/Syntheses_and_Anion_Binding_Capabilities_of_Bis_diarylboryl_Ferrocenes_and_Related_Systems/2415961 %R 10.1021/om400152x.s002 %2 https://acs.figshare.com/ndownloader/files/4057159 %K Anion Binding Capabilities %K electrophilic %K Synthese %K Bis %K fluoride %K combination %K Si %K substitution %K 1 equiv %K Lewis acid chelation %K acceptor %K none %K Ferrocene %K motif %K pattern %K Related SystemsIsomeric diborylated ferrocenes %X Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si–F–B bridging motif. %I ACS Publications