%0 Generic %A Zong, Jie %A Mague, Joel T. %A Pascal, Robert A. %D 2013 %T Exceptional Steric Congestion in an in,in-Bis(hydrosilane) %U https://acs.figshare.com/articles/dataset/Exceptional_Steric_Congestion_in_an_i_in_i_i_in_i_Bis_hydrosilane_/2378011 %R 10.1021/ja407398w.s002 %2 https://acs.figshare.com/ndownloader/files/4017634 %K combination %K characterization %K nonbonded %K Exceptional Steric Congestion %K crystallographically %K contact %K compound %K macrobicyclic %K data %K synthesis %X The synthesis and characterization of a macrobicyclic in,in-bis­(hydrosilane) is described. A combination of crystallographic and computational data indicate that the central hydrogen–hydrogen nonbonded contact distance is the shortest for any crystallographically characterized compound. %I ACS Publications