C–H
Activation of 2,4,6-Triphenylphosphinine:
Synthesis and Characterization of the First Homoleptic Phosphinine–Iridium(III)
Complex <i>fac</i>-[Ir(C^P)<sub>3</sub>]
Leen E.
E. Broeckx
Wylliam Delaunay
Camille Latouche
Martin Lutz
Abdou Boucekkine
Muriel Hissler
Christian Müller
10.1021/ic401933m.s001
https://acs.figshare.com/articles/journal_contribution/C_H_Activation_of_2_4_6_Triphenylphosphinine_Synthesis_and_Characterization_of_the_First_Homoleptic_Phosphinine_Iridium_III_Complex_i_fac_i_Ir_C_P_sub_3_sub_/2369695
Access to homoleptic phosphinine-based
coordination compounds of
d<sup>6</sup> metals has so far remained elusive. We report here on
the preparation and full characterization of the first homoleptic
phosphinine–iridium(III) complex, obtained by C–H activation
of 2,4,6-triphenylphosphinine with [Ir(acac)<sub>3</sub>]. This result
opens up new perspectives for the implementation of such aromatic
heterocycles in more applied research fields.
2016-02-18 17:50:04
characterization
Complex
triphenylphosphinine
coordination
Activation
Homoleptic
activation
Synthesi
Phosphinine
heterocycle
homoleptic
research fields
compound
fac
perspective
First
phosphinine
Characterization
Ir
preparation
implementation
Triphenylphosphinine
6 metals