10.1021/om4011164.s001
Yi-Sin Lin
Yi-Sin
Lin
Wen-Yann Yeh
Wen-Yann
Yeh
Unusual Coupling Reaction of C<sub>60</sub> and Benzonitrile
with Triosmium Carbonyls To Generate Fullerodiketimide Cluster Complexes
American Chemical Society
2014
Unusual
benzonitrile
Generate Fullerodiketimide Cluster ComplexesReaction
Benzonitrile
ligand
molecule
C 60
C 60 cage
fullerodiketimide
Carbonyl
reflux
solution
Triosmium
2014-02-10 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Unusual_Coupling_Reaction_of_C_sub_60_sub_and_Benzonitrile_with_Triosmium_Carbonyls_To_Generate_Fullerodiketimide_Cluster_Complexes/2324656
Reaction of Os<sub>3</sub>(CO)<sub>12</sub> (or Os<sub>3</sub>(CO)<sub>10</sub>(NCPh)<sub>2</sub>) with
C<sub>60</sub> in the benzonitrile/<i>o</i>-dichlorobenzene
solution at reflux produces Os<sub>3</sub>(CO)<sub>5</sub>(μ-NCHPh)(μ<sub>3</sub>,η<sup>5</sup>-NCPhC<sub>60</sub>C(C<sub>6</sub>H<sub>4</sub>)N)(μ,η<sup>4</sup>-C<sub>60</sub>) (<b>2</b>) and Os<sub>3</sub>(CO)<sub>4</sub>(NCPh)(μ-NCHPh)(μ<sub>3</sub>,η<sup>5</sup>-NCPhC<sub>60</sub>C(C<sub>6</sub>H<sub>4</sub>)N)(μ,η<sup>4</sup>-C<sub>60</sub>) (<b>3</b>), bearing an unprecedented
fullerodiketimide ligand from 1,4-addition of two benzonitrile molecules
to the C<sub>60</sub> cage.