%0 Generic
%A Zhang, Qiang
%A Peng, Hanqing
%A Zhang, Guishan
%A Lu, Qiongqiong
%A Chang, Jian
%A Dong, Yeye
%A Shi, Xianying
%A Wei, Junfa
%D 2014
%T Facile
Bottom-Up Synthesis of Coronene-based 3‑Fold
Symmetrical and Highly Substituted Nanographenes from Simple Aromatics
%U https://acs.figshare.com/articles/dataset/Facile_Bottom_Up_Synthesis_of_Coronene_based_3_Fold_Symmetrical_and_Highly_Substituted_Nanographenes_from_Simple_Aromatics/2310382
%R 10.1021/ja413018f.s003
%2 https://acs.figshare.com/ndownloader/files/3948007
%K AAA
%K modifiable
%K decoration
%K PAH
%K NG
%K Simple AromaticsA
%K FeCl
%K strategy
%K chemical
%K platform
%K Substituted Nanographenes
%K Synthesi
%K trithieno analogues
%K Facile
%K molecule
%K supramolecular architectures
%K CSA
%K construction
%K tenon joints
%K Symmetrical
%K analyses
%K benzylic carbons
%X A facile
and efficient self-sorting assemble (CSA) strategy has
been paved for bottom-up construction of the 3-fold symmetrical and
highly substituted hexa-cata-hexabenzocoronenes (c-HBCs), the trithieno analogues, and larger disc-shaped
PAHs from simple chemicals using benzylic carbons as tenon joints
and a novel FeCl3-mediated AAA process as a key step. The
structures of the as-prepared c-HBCs and related
NGs were clearly identified by spectral analyses and X-ray crystallographic
studies. Moreover, these can be envisaged to serve as new launching
platforms for the construction of larger and more complex π-conjugated
molecules and supramolecular architectures because of the modifiable
and symmetrical decorations.
%I ACS Publications