10.1021/ja5021348.s005
Jamie Hicks
Jamie
Hicks
Chad E. Hoyer
Chad E.
Hoyer
Boujemaa Moubaraki
Boujemaa
Moubaraki
Giovanni Li Manni
Giovanni Li
Manni
Emma Carter
Emma
Carter
Damien
M. Murphy
Damien
M.
Murphy
Keith S. Murray
Keith S.
Murray
Laura Gagliardi
Laura
Gagliardi
Cameron Jones
Cameron
Jones
A Two-Coordinate Manganese(0) Complex with an Unsupported
Mn–Mg Bond: Allowing Access to Low Coordinate Homo- and Heterobimetallic
Compounds
American Chemical Society
2016
C 6 H 2
Me
Mn
study details
Nacnac
2 CH
Heterobimetallic Compounds
Low Coordinate Homo
Ar
II
manganese
2016-04-06 16:33:39
Dataset
https://acs.figshare.com/articles/dataset/A_Two_Coordinate_Manganese_0_Complex_with_an_Unsupported_Mn_Mg_Bond_Allowing_Access_to_Low_Coordinate_Homo_and_Heterobimetallic_Compounds/2307271
This study details the synthesis and characterization of an unprecedented
two-coordinate, high-spin manganese(0) complex that incorporates an
unsupported Mn–Mg bond, viz. L<sup>†</sup>MnMg(<sup>Mes</sup>Nacnac) (L<sup>†</sup> = −N(Ar<sup>†</sup>)(SiPr<sup><i>i</i></sup><sub>3</sub>), Ar<sup>†</sup> = C<sub>6</sub>H<sub>2</sub>{C(H)Ph<sub>2</sub>}<sub>2</sub>Pr<sup><i>i</i></sup>-2,6,4; <sup>Mes</sup>Nacnac = [(MesNCMe)<sub>2</sub>CH]<sup>−</sup>; Mes = mesityl). This compound has
been utilized as an “inorganic Grignard reagent” in
the preparation of the first two-coordinate manganese(I) dimer, L<sup>†</sup>MnMnL* (L* = −N(Ar*)(SiMe<sub>3</sub>), Ar*
= C<sub>6</sub>H<sub>2</sub>{C(H)Ph<sub>2</sub>}<sub>2</sub>Me-2,6,4),
and the related mixed valence, bis(amido)-hetereobimetallic complex,
Mn<sup>II</sup>(μ-L<sup>†</sup>)(μ-L*)Cr<sup>0</sup>. It is also shown to act as a two-electron reducing agent in reactions
with unsaturated substrates.