%0 Journal Article
%A Fu, Hong-Ru
%A Kang, Yao
%A Zhang, Jian
%D 2014
%T Highly Selective Sorption of Small Hydrocarbons and
Photocatalytic Properties of Three Metal–Organic Frameworks
Based on Tris(4-(1H‑imidazol-1-yl)phenyl)amine
Ligand
%U https://acs.figshare.com/articles/journal_contribution/Highly_Selective_Sorption_of_Small_Hydrocarbons_and_Photocatalytic_Properties_of_Three_Metal_Organic_Frameworks_Based_on_Tris_4_1_i_H_i_imidazol_1_yl_phenyl_amine_Ligand/2304445
%R 10.1021/ic5003226.s001
%2 https://acs.figshare.com/ndownloader/files/3942079
%K Tipa
%K band gap
%K ligand
%K Framework
%K Selective Sorption
%K framework
%K compound
%K 2 D
%K Small Hydrocarbons
%K interpenetrating
%K LigandBy
%K Photocatalytic Properties
%K C 2H
%K solvothermally
%K CH 4.
%K bpdc
%K Compound 2
%K polycatenation
%K DMF
%K CO
%K Zn
%K exhibit
%K photocatalytic properties
%K tris
%K adsorption
%K Compound 1 features
%K biphenyldicarboxylate
%K Tris
%X By
employing a tris(4-(1H-imidazol-1-yl)phenyl)amine
(Tipa) ligand, three new metal–organic frameworks, [Zn2(Tipa)(4,4′-bpdc)1.5(H2O)(NO3)]·2(DMF)·H2O (1; 4,4′-bpdc
= 4,4′-biphenyldicarboxylate, DMF = N,N-dimenthylformamide), [Cd(Tipa)Cl2]·2(DMF)·H2O (2), and [Co(Tipa)Cl2(H2O)]·DMF·H2O (3), have been
synthesized solvothermally. Compound 1 features a three-dimensional
(3D) pillared-layer structure with low band gap and interesting photocatalytic
properties. Compound 2 is a 2-fold interpenetrating (3,6)-connected
porous framework, and it shows highly selective adsorption of C2H2, CO2, and C2H4 over CH4. Compound 3 with honeycomb-like
layers exhibits unusual 2D + 2D→ 3D polycatenation (2D = two-dimensional).
The luminescent properties for these compounds were also investigated.
%I ACS Publications