<i>In Situ</i> Transmission Electron Microscopy Observation of Electrochemical Sodiation of Individual Co<sub>9</sub>S<sub>8</sub>‑Filled Carbon Nanotubes
Qingmei Su
Gaohui Du
Jun Zhang
Yijun Zhong
Bingshe Xu
Yuehai Yang
Suman Neupane
Wenzhi Li
10.1021/nn500194q.s003
https://acs.figshare.com/articles/media/_i_In_Situ_i_Transmission_Electron_Microscopy_Observation_of_Electrochemical_Sodiation_of_Individual_Co_sub_9_sub_S_sub_8_sub_Filled_Carbon_Nanotubes/2304127
The comprehension of fundamental electrochemical behavior and sodiation mechanism is critical for the design of high-performance electrode materials for sodium-ion (Na-ion) batteries. In this paper, the electrochemical sodiation process and microstructure evolution of individual Co<sub>9</sub>S<sub>8</sub>-filled carbon nanotubes (CNTs) have been directly visualized and studied using <i>in situ</i> transmission electron microscopy. Upon the first sodiation, a reaction front propagates progressively along the filling nanowire, causing the filled CNT to inflate. The filled CNTs behave differently depending on their structures and the magnitude of the sodiation voltage. For a Co<sub>9</sub>S<sub>8</sub>-filled CNT with an open end, the sodiated Co<sub>9</sub>S<sub>8</sub> filler shows a substantial axial elongation of 120.8% and a small radial swelling due to the extrusion of CNT walls. In contrast, the closed CNT shows a major radial expansion of 40.6% and a small axial elongation because of the mechanical confinement of the carbon shells. After sodiation, the spacing between the carbon shells increases from 3.4 to 3.8 Å due to the Na<sup>+</sup>-ion insertion and the single-crystalline Co<sub>9</sub>S<sub>8</sub> filler converts to numerous Co nanograins dispersed in a Na<sub>2</sub>S matrix. Compared with the gentle microstructure evolution of the CNT under small charging voltage, a strong electrochemical reaction accompanying drastic swelling and fracturing of CNT shells is observed for the CNT electrode under large charging voltage. Our observations provide direct evidence and important insights for the electrochemical process of CNT-based composite materials in Na-ion batteries.
2014-04-22 00:00:00
Situ Transmission Electron Microscopy Observation
reaction front propagates
Co 9S CNT
microstructure evolution
Na 2S matrix
transmission electron microscopy
sodiated Co 9S filler
electrochemical sodiation process
Individual Co 9S Carbon NanotubesThe comprehension
Co 9S carbon nanotubes
carbon shells increases