Vapor Condensed and Supercooled Glassy Nanoclusters Weikai Qi Richard K. Bowles 10.1021/acsnano.5b07391.s001 https://acs.figshare.com/articles/journal_contribution/Vapor_Condensed_and_Supercooled_Glassy_Nanoclusters/2299672 We use molecular simulation to study the structural and dynamic properties of glassy nanoclusters formed both through the direct condensation of the vapor below the glass transition temperature, without the presence of a substrate, and via the slow supercooling of unsupported liquid nanodroplets. An analysis of local structure using Voronoi polyhedra shows that the energetic stability of the clusters is characterized by a large, increasing fraction of bicapped square antiprism motifs. We also show that nanoclusters with similar inherent structure energies are structurally similar, independent of their history, which suggests the supercooled clusters access the same low energy regions of the potential energy landscape as the vapor condensed clusters despite their different methods of formation. By measuring the intermediate scattering function at different radii from the cluster center, we find that the relaxation dynamics of the clusters are inhomogeneous, with the core becoming glassy above the glass transition temperature while the surface remains mobile at low temperatures. This helps the clusters sample the highly stable, low energy structures on the potential energy surface. Our work suggests the nanocluster systems are structurally more stable than the ultrastable glassy thin films, formed through vapor deposition onto a cold substrate, but the nanoclusters do not exhibit the superheating effects characteristic of the ultrastable glass states. 2016-02-11 00:00:00 energy regions ultrastable glass states bicapped square antiprism motifs superheating effects glass transition temperature cluster center vapor deposition energy landscape supercooled clusters access clusters sample Voronoi polyhedra energy surface Supercooled Glassy Nanoclusters structure energies relaxation dynamics nanocluster systems Vapor Condensed energy structures